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328774

Aldrich

 

Tris(dibenzylideneacetone)dipalladium(0)

CAS Number:51364-51-3
Linear Formula:(C6H5CH=CHCOCH=CHC6H5)3Pd2
Molecular Weight:915.72
MDL number:MFCD00013310
PubChem Substance ID:24859746

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Description

ApplicationCatalyst for [2+2+2] cycloaddtion of didehydrotriphenylenes to the corresponding extended triphenylenes.1
Catalyst for the carbonylation of β,β-imidoyl iodides to the corresponding imidate esters used, in turn, to prepare cyclic, quaternary amino acids.2
 Catalyst for cross-coupling reactions.3,4
Packaging1, 5, 50, 100 g in glass btl
 500 mg in glass btl

Properties

mp152-155 °C(lit.)

Safety

Personal Protective EquipmentEyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
WGK Germany2

References

Cited Reference1. Chem. Eur. J. 12, 5657, (2006)
 2. Org. Lett. 8, 4129, (2006) Abstract
 3. Eur. J. Inorg. Chem. 6, 1262-1269, (2004)
 4. Eur. J. Org. Chem. 10, 2214-2222, (2004)
reference Tetrahedron Lett. 33, 4859, (1992)
FieserFieser 17,394
 RegBook 1 (2), 3103:G / Structure Index 1, 491:D:8